Chemistry

Weak Acid pH Calculator (from Ka or pKa)

Enter a weak acid’s concentration and Ka (or pKa) to get the pH.

Your numbers

Your results

pH
pH
—
[H⁺] (mol/L)
—
Percent ionised
—
pH by the √(Ka·c) shortcut
—
pKa
—

Weak Acid pH Calculator (from Ka or pKa) by TheCalcTools

How the Weak Acid pH Calculator (from Ka or pKa) works

A weak acid HA only partly ionises: Ka = [H⁺][A⁻] ÷ [HA]. With x = [H⁺], x² ÷ (c − x) = Ka, which the calculator solves exactly with the quadratic formula.

The common shortcut x ≈ √(Ka × c) works when less than about 5% of the acid ionises. Water’s own ionisation is ignored, which is fine unless the acid is extremely dilute.

The formula

[H⁺] = (−Ka + √(Ka² + 4 Ka c)) ÷ 2; pH = −log₁₀[H⁺]

Worked example

Using the default values shown in the calculator:

Strength given aspKa
pKa4.76
Ka1.75e-05
Concentration (mol/L)0.1
  1. Acetic acid, pKa 4.76, 0.1 M: [H⁺] = 0.00131 mol/L.
  2. pH = 2.88, with 1.31% ionised.

Result:

pH2.883
[H⁺] (mol/L)0.00131
Percent ionised1.31%
pH by the √(Ka·c) shortcut2.880
pKa4.760

Frequently asked questions

What is the pH of 0.1 M acetic acid?

About 2.88, with Ka = 1.75 × 10⁻⁵ (pKa 4.76).

Sources and further reading

More in Chemistry · All calculators

This calculator gives estimates for information only. Check important results independently before you rely on them. See our disclaimer.